Тип публикации: статья из журнала
Год издания: 2026
Идентификатор DOI: 10.3390/ma19030446
Аннотация: <jats:p>This review provides a comparative analysis of the structure and physical properties of low-dimensional aperiodic crystalline solids, aiming to elucidate the origin and nature of aperiodicity in reduced-dimensional lattices. The breakdown of periodicity in low-dimensional systems arises from several mechanisms, including thПоказать полностьюe suppression of specific force constants, thermodynamic instabilities, and topological constraints associated with imperfect space filling. At the nanoscale, certain cubic crystalline materials can form finite, zero-dimensional multiply twinned particles (MTPs) with decahedral or icosahedral symmetry. These clusters lack translational invariance and experience intrinsic structural strain due to solid-angle mismatch at twin junctions, which limits their characteristic size and renders them finite aperiodic solids. Particular attention is devoted to the electronic and spin properties of pentagonally symmetric MTPs: icosahedral particles exhibit symmetry-protected spin degeneracy consistent with centrosymmetric lattices, whereas non-centrosymmetric decahedral particles may display spin polarization and emergent low-dimensional magnetism. Collectively, these systems illustrate the diverse physical origins, manifestations, and consequences of aperiodicity in low-dimensional crystalline matter.</jats:p>
Журнал: Materials
Выпуск журнала: Т. 19, № 3
Номера страниц: 446
ISSN журнала: 19961944
Место издания: Basel