Тип публикации: статья из журнала
Год издания: 2011
Идентификатор DOI: 10.1134/S0023158411020145
Аннотация: For three 6?-cyanosubstituted spironaphthooxazines, spectral characteristics of an open form and quantum yields of photoisomerization were determined both at room temperature and in frozen alcohol matrices. Spironaphthooxazines have demonstrated fairly high (0.01-0.02) quantum yields of open form appearance at 77 K. The observed peПоказать полностьюculiarities of the open form UV spectra were explained by the temperature dependence of the open form isomers distribution. Partial stabilization of the nonequilibrium isomers of an open form in the low-temperature matrices was revealed. © 2011 Pleiades Publishing, Ltd.
Журнал: Kinetics and Catalysis
Выпуск журнала: Vol. 52, Is. 2
Номера страниц: 202-209