Novel Cr3+-Doped Garnet Phosphor with Broadband Efficient Far-Red Emission for Photochrome Matching Plant-Lighting

Описание

Тип публикации: статья из журнала

Год издания: 2023

Идентификатор DOI: 10.1002/adom.202302380

Аннотация: <jats:title>Abstract</jats:title><jats:p>Cr<jats:sup>3+</jats:sup>-doped phosphors are highly recognized in various fields for their remarkable luminous efficiency and spectral flexibility, including modern agriculture and horticulture. However, the shortage of suitable Cr<jats:sup>3+</jats:sup>-doped phosphors for far-red LED deviПоказать полностьюces has inhibited their popularization in plant lighting. Herein, an innovative Cr<jats:sup>3+</jats:sup>-doped phosphor Ca<jats:sub>2</jats:sub>YAl<jats:sub>3</jats:sub>Ge<jats:sub>2</jats:sub>O<jats:sub>12</jats:sub>:Cr<jats:sup>3+</jats:sup> (CYAG:Cr<jats:sup>3+</jats:sup>), achieving a broad far-red emission at 770 nm upon 450 nm blue light excitation is designed. The optimal CYAG:Cr<jats:sup>3+</jats:sup> phosphor exhibits a high internal quantum yield of 78.2% and low thermal-quenching behavior of 85%@373 K. Thus, the fabricated phosphor-converted LEDs (pc-LEDs) for plant far-red lighting have a high output power of 33.3 mW and photovoltaic conversion efficiency of 11.5% at 100 mA. The potential of CYAG:Cr<jats:sup>3+</jats:sup> in plant lighting is assessed by supplementing the far-red lighting of Italian lettuce with fabricated pc-LEDs, and the biomass of Italian lettuce is significantly increased by 33%. The successful development of CYAG:Cr<jats:sup>3+</jats:sup> phosphors provides a high-quality option for plant far-red light devices and further stimulates the development of new Cr<jats:sup>3+</jats:sup>-doped plant-lighting phosphors.</jats:p>

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Издание

Журнал: Advanced Optical Materials

ISSN журнала: 21951071

Персоны

  • Dai Xiangyi (Key Laboratory for Biobased Materials and Energy of Ministry of Education College of Materials and Energy South China Agricultural University Guangzhou Guangdong 510642 P. R. China)
  • Zou Xikun (Key Laboratory for Biobased Materials and Energy of Ministry of Education College of Materials and Energy South China Agricultural University Guangzhou Guangdong 510642 P. R. China)
  • Zhang Haoran (Maoming Branch Guangdong Laboratory for Lingnan Modern Agriculture Maoming Guangdong 25100 P. R. China)
  • Chen Weibin (Key Laboratory for Biobased Materials and Energy of Ministry of Education College of Materials and Energy South China Agricultural University Guangzhou Guangdong 510642 P. R. China)
  • Yang Chaowei (Key Laboratory for Biobased Materials and Energy of Ministry of Education College of Materials and Energy South China Agricultural University Guangzhou Guangdong 510642 P. R. China)
  • Molokeev Maxim S. (SB RAS Kirensky Inst Phys Lab Crystal Phys Krasnoyarsk 660036 Russia)
  • Xia Zhiguo (The State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques School of Physics and Optoelectronics South China University of Technology Guangzhou 510641 P. R. China)
  • Liu Yingliang (Key Laboratory for Biobased Materials and Energy of Ministry of Education College of Materials and Energy South China Agricultural University Guangzhou Guangdong 510642 P. R. China)
  • Zhang Xuejie (Maoming Branch Guangdong Laboratory for Lingnan Modern Agriculture Maoming Guangdong 25100 P. R. China)
  • Zheng Mingtao (Maoming Branch Guangdong Laboratory for Lingnan Modern Agriculture Maoming Guangdong 25100 P. R. China)
  • Lei Bingfu (Maoming Branch Guangdong Laboratory for Lingnan Modern Agriculture Maoming Guangdong 25100 P. R. China)

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