Тип публикации: статья из журнала

Год издания: 2023

Идентификатор DOI: 10.3390/micro3040063

Аннотация: <jats:p>The functionalization of copolyfluorenes containing dicyanophenanthrene units by closo-decaborate anion is described. Target copolyfluorenes were analyzed using SEM, UV-vis, luminescence, NMR, and Fourier-transform infrared (FTIR) spectroscopy. The effect of complexation with the closo-decaborate anion on the photophysical Показать полностьюproperties was studied both experimentally and theoretically. The PL data indicate an efficient charge transfer from fluorene to the dicyanophenanthrene units coordinated to the closo-decaborate. The coordination of closo-decaborate clusters to the nitrile groups of copolyfluorenes provides an important route to new materials for sensors and light-emitting devices while, at the same time, serving as a platform for further study of the nature of boron clusters.</jats:p>

Журнал: Micro

Выпуск журнала: Т. 3, № 4

Номера страниц: 930-940

ISSN журнала: 26738023

Место издания: Basel

Издатель: MDPI

• Yakimanskiy Anton A. (Institute of Macromolecular Compounds, RAS, Bolshoi Prospect of Vasilyevsky Island 31, Saint Petersburg 199004, Russia)
• Kaskevich Ksenia I. (Institute of Macromolecular Compounds, RAS, Bolshoi Prospect of Vasilyevsky Island 31, Saint Petersburg 199004, Russia)
• Chulkova Tatiana G. (Institute of Macromolecular Compounds, RAS, Bolshoi Prospect of Vasilyevsky Island 31, Saint Petersburg 199004, Russia)
• Krasnopeeva Elena L. (Institute of Macromolecular Compounds, RAS, Bolshoi Prospect of Vasilyevsky Island 31, Saint Petersburg 199004, Russia)
• Savilov Serguei V. (Kurnakov Institute of General and Inorganic Chemistry, RAS, Moscow 119991, Russia)
• Voinova Vera V. (Kurnakov Institute of General and Inorganic Chemistry, RAS, Moscow 119991, Russia)
• Neumolotov Nikolay K. (Kurnakov Institute of General and Inorganic Chemistry, RAS, Moscow 119991, Russia)
• Zhdanov Andrey P. (Kurnakov Institute of General and Inorganic Chemistry, RAS, Moscow 119991, Russia)
• Rogova Anastasia V. (Laboratory for Digital Controlled Drugs and Theranostics, Federal Research Center KSC SB RAS, Krasnoyarsk 660041, Russia)
• Tomilin Felix N. (Laboratory for Digital Controlled Drugs and Theranostics, Federal Research Center KSC SB RAS, Krasnoyarsk 660041, Russia)
• Zhizhin Konstantin Yu. (Kurnakov Institute of General and Inorganic Chemistry, RAS, Moscow 119991, Russia)
• Yakimansky Alexander V. (Institute of Macromolecular Compounds, RAS, Bolshoi Prospect of Vasilyevsky Island 31, Saint Petersburg 199004, Russia)

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