Apatite oxynitride phosphor (Mg,Y)5Si3(O,N)13:Ce3+,Mn2+: A single-phased host with solar-like and efficient emission

Описание

Тип публикации: статья из журнала

Год издания: 2023

Идентификатор DOI: 10.1111/jace.18981

Аннотация: <jats:title>Abstract</jats:title><jats:p>During pursuing high color rendering index for full-color-emitting phosphor, low quantum efficiency (QE) is usually accompanying. We intend to elevate the luminescence efficiency when realizing a solar-like spectra distribution, by constructing apatite structure oxynitride, inheriting high cПоказать полностьюovalence and rigidity from oxynitride, and suitable multiple cation sites from oxyapatite compounds. Full-color-emitting apatite structure oxynitride phosphor (Mg,Y)<jats:sub>5</jats:sub>Si<jats:sub>3</jats:sub>(O,N)<jats:sub>13</jats:sub>:Ce<jats:sup>3+</jats:sup>,Mn<jats:sup>2+</jats:sup> has been prepared, and the crystal sites’ occupancies of activators in this host were favorable for white emission. (Mg,Y)<jats:sub>5</jats:sub>Si<jats:sub>3</jats:sub>(O,N)<jats:sub>13</jats:sub>:Ce<jats:sup>3+</jats:sup>,Mn<jats:sup>2+</jats:sup> phosphor shows whole visible light with emission wavelength ranging from 370 to 750 nm, matching the spectra of sunlight quite well. The fabricated white light-emitting diode lamp demonstrated the distinctive overall performance of QE and chromaticity properties (<jats:italic>R</jats:italic><jats:sub>a</jats:sub> and <jats:italic>R</jats:italic><jats:sub>9</jats:sub>). Furthermore, correlated color temperature is tunable from cool nature to warm white. The obtained lamp possesses the feature of less blue light hazard and high saturation of red degree, compared with the commercial YAG-based lamp.</jats:p>

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Издание

Журнал: Journal of the American Ceramic Society

Выпуск журнала: Т. 106, 5

Номера страниц: 2985-2996

ISSN журнала: 00027820

Издатель: American Ceramic Society

Персоны

  • Wu Yanzheng (College of Chemical Engineering Zhejiang University of Technology Hangzhou China)
  • Li Weiqiang (College of Chemical Engineering Zhejiang University of Technology Hangzhou China)
  • Zheng Yifan (Research Center of Analysis and Measurement Zhejiang University of Technology Hangzhou China)
  • Xu Yiqin (Institute of Semiconductors Guangdong Academy of Sciences Guangzhou China)
  • Wen Dawei (School of Applied Physics and Materials Wuyi University Jiangmen Guangdong China)
  • Molokeev Maxim S. (Laboratory of Crystal Physics Kirensky Institute of Physics Federal Research Center KSC SB RAS Krasnoyarsk Russia)
  • Pan Zaifa (College of Chemical Engineering Zhejiang University of Technology Hangzhou China)

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