Synthesis and structure of tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane

Описание

Тип публикации: статья из журнала

Год издания: 2022

Идентификатор DOI: 10.1016/j.mencom.2022.05.029

Ключевые слова: alkynes, organogermanium compounds, organosilicon compounds, quantum chemical calculations, x-ray analysis

Аннотация: Tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane were synthesized by the reaction of BrMgC[tbnd]CSi(CH2Cl)Me2 with SiCl4/GeCl4. Their structures were proved by IR, NMR spectroscopy and X-ray analysis, and compared to the results of MP2/6-311G(d,p) calculations. © 2022

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Издание

Журнал: Mendeleev Communications

Выпуск журнала: Vol. 32, Is. 3

Номера страниц: 379-381

ISSN журнала: 09599436

Издатель: Elsevier Ltd

Персоны

  • Yarosh N.O. (A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, 664033, Russian Federation)
  • Zhilitskaya L.V. (A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, 664033, Russian Federation)
  • Sterkhova I.V. (A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, 664033, Russian Federation)
  • Plyaskin M.E. (Siberian Federal University, Krasnoyarsk, 660041, Russian Federation, L. V. Kirensky Institute of Physics, Federal Research Center KSC, Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation)
  • Shainyan B.A. (A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, 664033, Russian Federation)

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