The effect of solvents on the stability of the products of electrochemical reactions of iron, ruthenium, and osmium carbonyl cluster compounds

Описание

Тип публикации: статья из журнала

Год издания: 2012

Идентификатор DOI: 10.1134/S0036023612050051

Ключевые слова: Aprotic solvents, Carbonyl cluster compounds, Electrochemical reactions, Osmium carbonyl clusters, Tetra-hydrofuran, Acetone, Acetonitrile, Dichloromethane, Electrochemical corrosion, Osmium, Ruthenium, Solvents, Organic solvents

Аннотация: The electrochemical reactions of carbonyl cluster compounds M-3(CO)(12) (M = Fe, Ru, Os) were compared with those of [Fe5C(CO)(14)](2-) and [Fe6C(CO)(16)](2-) in different aprotic solvents. The stability of electrochemically generated products of these clusters in the studied solvents was shown to grow in the following order: tetraПоказать полностьюhydrofuran

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Издание

Журнал: RUSSIAN JOURNAL OF INORGANIC CHEMISTRY

Выпуск журнала: Vol. 57, Is. 8

Номера страниц: 1154-1157

ISSN журнала: 00360236

Место издания: NEW YORK

Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER

Персоны

  • Burmakinaa G.V. (Siberian Federal University)
  • Rubailoa A.I. (Siberian Federal University)
  • Pavlenkob N.I. (Institute of Chemistry and Chemical Technology,Siberian Branch,Russian Academy of Sciences)

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