Study of Structural and Catalytic Properties of Pt/WOx/ZrO2, Modified by Lanthanum Cations : научное издание

Описание

Тип публикации: научное издание

Год издания: 2020

Идентификатор DOI: 10.17516/1998-2836-0161

Ключевые слова: tungstated zirconia catalyst; cation-modified zirconium dioxide; lanthanum; phase composition; hydroisomerization; n-heptane; benzene, benzene, cation-modified zirconium dioxide, hydroisomerization, lanthanum, n-heptane, phase composition, tungstated zirconia catalyst

Аннотация: The effect of the addition of La3+ cations on the structural properties of Pt/WOx/ZrO2 catalysts and the characteristics of catalytic activity in the process of hydroisomerization of n-heptane and benzene mixture was studied. The phase composition of the catalysts is represented by a solid solution of lanthanum cations in nanocrystПоказать полностьюalline zirconia of tetragonal modification with localization of lanthanum in the surface layers predominantly. The positive effect of La3+ additives on the selectivity and yield of isomerized products was shown. The effect of the addition of La3+ cations on the structural properties of Pt/WOх/ZrO2 catalysts and the characteristics of catalytic activity in the process of hydroisomerization of n-heptane and benzene mixture was studied. The phase composition of the catalysts is represented by a solid solution of lanthanum cations in nanocrystalline zirconia of tetragonal modification with localization of lanthanum in the surface layers predominantly. The positive effect of La3+ additives on the selectivity and yield of isomerized products was shown. © Siberian Federal University. All rights reserved

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Издание

Журнал: JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY

Выпуск журнала: Vol. 13, is. 1

Номера страниц: 133-141

ISSN журнала: 19982836

Место издания: KRASNOYARSK

Персоны

  • Naumova Svetlana A. (FRC Krasnoyarsk Sci Ctr SB RAS, Inst Chem & Chem Technol SB RAS, Krasnoyarsk, Russia; Siberian Fed Univ, Krasnoyarsk, Russia)
  • Obukhova Anastasia V. (FRC Krasnoyarsk Sci Ctr SB RAS, Inst Chem & Chem Technol SB RAS, Krasnoyarsk, Russia)
  • Kuznetsova Ludmila I. (FRC Krasnoyarsk Sci Ctr SB RAS, Inst Chem & Chem Technol SB RAS, Krasnoyarsk, Russia)

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