Тип публикации: статья из журнала

Год издания: 2010

Идентификатор DOI: 10.1103/PhysRevLett.105.233001

Аннотация: Dissociative nuclear motion in core-excited molecular states leads to a splitting of the fragment Auger lines: the Auger-Doppler effect. We present here for the first time experimental evidence for an Auger-Doppler effect following F1s→a1g* inner-shell excitation by circularly polarized x rays in SF₆. In spite of a uniform distribution of the dissociating S-F bonds near the polarization plane of the light, the intersection between the subpopulation of molecules selected by the core excitation with the cone of dissociation induces a strong anisotropy in the distribution of the S-F bonds that contributes to the scattering profile measured in the polarization plane. © 2010 The American Physical Society.

Журнал: Physical Review Letters

Выпуск журнала: Т. 105, № 23

Номера страниц: 233001

ISSN журнала: 00319007

Издатель: American Physical Society

• Travnikova O. (Synchrotron SOLEIL,L'Orme des Merisiers, Saint-Aubin)
• Lindblad A. (Synchrotron SOLEIL,L'Orme des Merisiers, Saint-Aubin)
• Nicolas C. (Synchrotron SOLEIL,L'Orme des Merisiers, Saint-Aubin)
• Söderström J. (Synchrotron SOLEIL,L'Orme des Merisiers, Saint-Aubin)
• Kimberg V. (Synchrotron SOLEIL,L'Orme des Merisiers, Saint-Aubin)
• Miron C. (Synchrotron SOLEIL,L'Orme des Merisiers, Saint-Aubin)
• Liu J. C. (Department of Theoretical Chemistry,Royal Institute of Technology)
• Gel'Mukhanov F. (Department of Theoretical Chemistry,Royal Institute of Technology)

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